Product ID:C-147 CARPENTER'S WOOD FILLER, CAULKS, (SUPDAT)
MSDS Date:11/01/1995
FSC:8030
NIIN:00N060793
MSDS Number: CGZTD

SHERWIN-WILLIAMS CO

101 PROSPECT AVE
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 15%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST;9495

CLAY (KAOLIN); (KAOLIN)

CAS: 1332-58-7

RTECS: GF1670500

Fraction By Weight: 10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 2 MG/M3 TDUST; 9495

1); (CALCIUM CARBONATE)

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 35%

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY

RTECS: 9999999ZZ

LUNG).

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION
MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. SIGNS AND SYMPTOMS OF
OVEREXPOSURE: REDNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: LONG TERM
EXPOSURE TO (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE QUARTZ: IARC
MONOGRAPHS, VOL 68, 1997: GRP 1. NTP 7TH ANNUAL RPT ON CARCIN,
1994: ANTIC (ING 5)
Effects of Overexposure:HLTH HAZ: HIGH LEVELS OF SILICA DUST, WHICH CAN
OCCUR ONLY WHERE SANDING OR ABRADING THE DRY FILM, MAY CAUSE LUNG
DAMAGE (SILICOSIS) AND POSSIBLY CANCER.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH
EYES W ITH LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET
MEDICAL ATTENTION. INGEST: SEEK MEDICAL ATTENTION IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:VENTILATE AND REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN. CA PROPOSITION 65:
WARNING: THESE PRODUCTS, EXCEPT FOR C-99, CONTAIN A CHEMICAL(S)
KNOWN TO THE STATE OF CA TO CAUSE CANCER.

Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN
SANDING/ABRADING DRIED FILM, WEA R A DUST/MIST RESP APPRVD (SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF THE EXPOS TO MATLS
IN SECTION 2 IS MAINTAINED BELOW APPLIC EXPOS LIMS. (SUPDAT)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:SPACKLING COMPOUNDS, FILLER & SEALANTS. FIRE
FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION
WHEN EXPOSED TO EXTREME HEAT. VENT: REFER TO OSHA STDS 1910.94, 19
10.107, 1910.108. RESP PROT:BY NIOSH FOR PROT AGAINST MATLS IN
SECTION II. WHEN SANDING/ABRADING THE DRIED (ING 4)

Boiling Pt:B.P. Text:>212F,>100C
Vapor Density:HVR/AIR
Spec Gravity:13.7
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODUCT IS NOT HAZARDOUS AS
DEFINED UNDER THE RCRA 40 CFR 261. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION.

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This information is formulated for use by elements of the Department
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document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.